Note4Students
From UPSC perspective, the following things are important :
Prelims level: Electric Batteries
Mains level: Not Much
Central Idea
- Electric batteries have become an integral part of modern life, enabling the widespread use of motorization and wireless technology.
- These devices store and release electrical energy, acquired by converting other forms of energy, primarily through chemical reactions.
Historical Roots of Electric Batteries
- Galvani’s Experiment: In 1780, Luigi Galvani conducted an experiment involving two metal plates and a frog’s leg, marking an early exploration of electricity’s effects on biological systems.
- Volta’s Voltaic Pile: Alessandro Volta’s voltaic pile in 1800 consisted of alternating copper and zinc plates separated by electrolyte-soaked paper. It produced a steady current but lacked a comprehensive explanation.
- John Daniel’s Innovation: British chemist John Daniel improved on Volta’s design with a more efficient cell that generated electric current for extended periods.
- Faraday’s Insights: In the early 19th century, Michael Faraday elucidated the principles of electrochemical cells, including naming components like anode, cathode, and electrolyte.
Understanding Electric Batteries
- Voltaic Cells: Electric batteries, also known as voltaic or galvanic cells, utilize redox reactions to produce an electric current. They consist of two half-cells, each with a metal electrode immersed in an electrolyte of the same metal.
- Electron Transfer: In one half-cell, metal ions dissolve into the electrolyte, releasing electrons. In the other half-cell, the reverse occurs, as metal ions deposit onto the electrode and require electrons.
- External Circuit: A wire connects the two electrodes, allowing electron flow from the anode to the cathode. A salt bridge connects the two electrolytes, enabling ion exchange.
- Components: Key components include the cathode (positive electrode), anode (negative electrode), and the electrolyte. The source voltage and terminal voltage are important concepts.
- Source Voltage: It represents the energy imparted to electrons and is equal to the terminal voltage in ideal conditions.
- Issues: Corrosion is a common issue in electrochemical cells, caused by factors like moisture and galvanic corrosion.
Types of Batteries
- Lithium-Ion (Li-ion) Batteries: Li-ion batteries are rechargeable and have revolutionized technology. They consist of a cathode, anode, and an electrolyte. During discharge, lithium ions move between electrodes, facilitating energy storage.
- Electric Vehicle (EV) Batteries: EV batteries, such as those used in Tesla’s Model S, are composed of numerous Li-ion cells and are critical for powering electric vehicles.
- Hydrogen Fuel Cells: Hydrogen fuel cells are gaining interest, especially in the context of green energy. They use hydrogen as a fuel source and produce electricity through a chemical reaction with oxygen, emitting water as a byproduct.
Future Prospects and Significance
- Ongoing Research: Li-ion batteries and hydrogen fuel cells continue to be areas of extensive research, with diverse configurations and advantages.
- Hydrogen Economy: Hydrogen fuel cells are expected to play a pivotal role in the emerging hydrogen economy, and countries like India are investing in green hydrogen production.
Conclusion
- Electric batteries, rooted in the principles of electrochemistry, have undergone significant evolution, transforming the way we live and utilize energy.
- Their development and improvement remain central to advancing convenience and sustainability in industrialized societies, shaping the future of technology and transportation.
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