Note4Students
From UPSC perspective, the following things are important :
Prelims level: Superconductivity, LK-99
Mains level: Read the attached story
Introduction
- A group of scientists from China and Japan have reported findings that could indicate superconductivity in a controversial material.
What is Superconductivity?
- Zero Resistance: Superconductivity occurs when a material offers almost zero resistance to the flow of electric current, enabling energy-efficient electrical appliances and lossless power transmission.
- Magnetic Behavior: Superconductors also display fascinating behavior under magnetic fields, enabling technologies like MRI machines and superfast Maglev trains.
Exploring the Material LK-99
- Apatite Structure: The Korean group utilized copper-substituted lead apatite, a phosphate mineral with unique tetrahedral motifs, to create LK-99.
- Superconducting Behavior: LK-99 displayed essential superconducting properties, with almost zero resistance to current flow and sudden emergence of resistance above a critical current threshold.
- Magnetic Resilience: LK-99 retained superconductivity even under the presence of a magnetic field until reaching a critical threshold.
Meissner Effect: Key Indicator of Superconductivity
- Definition: The Meissner effect is a phenomenon where materials expel magnetic fields from their interior upon becoming superconductors.
- Observation in Study: The researchers observed this effect in copper-substituted lead apatite, suggesting potential superconductivity.
Quest for Room-Temperature Superconductors
- Significance: Discovering a material that is superconducting at room temperature and pressure (RTP) has immense scientific and commercial value.
- Applications: RTP superconductors could revolutionize power transmission, medical diagnostics, computing, and more, due to their ability to conduct electricity without loss.
Hype and Controversies in Superconductivity Research
- Past Controversies: The field has seen several disputes, including claims by Ranga Dias and a South Korean research group, which were later contested.
- Impact of Hype: The lucrative potential of RTP superconductors has sometimes led to premature claims and controversies in the scientific community.
New Study: Methodology and Findings
- Approach: The team synthesized LK-99 samples using advanced techniques and tested for signs of superconductivity beyond specific claims made by previous studies.
- Direct Current Measurements: They conducted hysteresis experiments, applying and removing a magnetic field to observe the material’s response at various temperatures.
Understanding Hysteresis in Superconductors
- Meissner Effect and DC Current: The Meissner effect is observable with direct current, as alternating current would disrupt the phenomenon.
- Type I and II Superconductors: The study helps distinguish between these types based on how they respond to increasing magnetic field strength.
Challenges and Limitations of the Study
- Small Superconducting Portions: The material’s superconducting sections were small, leading to a low critical magnetic field strength.
- Interference Issues: The presence of cuprous sulphide interfered with molecular structure analysis using X-rays.
Way Forward: Verifying RTP Superconductivity
- Potential for RTP Superconductivity: While the study suggests near-RTP superconductivity in LK-99, definitive observation is yet to be made.
- Need for Further Research: Identifying the material responsible for superconductivity and refining synthesis techniques are crucial next steps.
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